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Defects and charge transport in Mn-doped K0.5Na0.5NbO3 ceramics

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Phys. Chem. Chem. Phys., 2015, Advance Article
DOI: 10.1039/C5CP02883C, Paper
Muhammad Asif Rafiq, Alexander Tkach, Maria Elisabete Costa, Paula Maria Vilarinho
KNN room-temperature conduction is associated with hole transport and can be suppressed by Mn-doping; a less leaky hysteresis loop is obtained. At high temperatures conduction is dominated by ionized oxygen vacancies motion. From grains and grain-boundaries resistance oxygen vacancies in KNN and Mn-doped KNN ceramics are mainly located at grain-boundaries.
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