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Formation and nitrile hydrogenation performance of Ru nanoparticles on a K-doped Al2O3 surface

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Phys. Chem. Chem. Phys., 2015, 17,24791-24802
DOI: 10.1039/C5CP03456F, Paper
Satoshi Muratsugu, Sutasinee Kityakarn, Fei Wang, Nozomu Ishiguro, Takashi Kamachi, Kazunari Yoshizawa, Oki Sekizawa, Tomoya Uruga, Mizuki Tada
Decarbonylation-promoted Ru nanoparticle formation from Ru3(CO)12 on a basic K-doped Al2O3 surface was investigated by in situ FT-IR and in situ XAFS. The prepared Ru nanoparticle acted as an efficient catalyst for nitrile hydrogenation to primary amine.
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