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Towards the rationalization of catalytic activity values by means of local hyper-softness on the catalytic site: a criticism about the use of net electric charges

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Phys. Chem. Chem. Phys., 2015, Advance Article
DOI: 10.1039/C5CP03822G, Paper
Jorge Ignacio Martinez-Araya, Andre Grand, Daniel Glossman-Mitnik
The Spin-Polarized Conceptual Density Functional Theory (SP-CDFT) provides a local reactivity descriptor that after being assessed on the catalytic site (Fe) tends to be proportional to catalytic activity in a better way than the net electric charge computed on the same site. For this aim three 2,6-bis(imino)pyridil iron(III) cationic catalysts, used for the polymerization of ethylene, were studied.
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