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Conformational preferences of monohydrated clusters of imidazole derivatives revisited

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Phys. Chem. Chem. Phys., 2015, 17,20080-20092
DOI: 10.1039/C5CP02422F, Paper
Aditi Bhattacherjee, Sanjay Wategaonkar
IR-UV double resonance spectroscopy was used to identify the conformers of monohydrated benzimidazole and N-methylbenzimidazole in a supersonic jet. A new OH-N bound conformer relevant to histidine containing proteins was discovered. The long standing differences in the literature about the relative energies and abundance of the monohydrated imidazole derivatives have also been resolved.
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