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The pH dependence of OH radical formation in photo-electrochemical water oxidation with rutile TiO2 single crystals

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Phys. Chem. Chem. Phys., 2015, Advance Article
DOI: 10.1039/C5CP04531B, Paper
Yukihiro Nakabayashi, Yoshio Nosaka
The experimental results in photoelectrolysis with rutile (100) and (110) TiO2 single crystals support a plausible reaction mechanism that the surface Ti-O-O-Ti structure is an intermediate of water oxidation process, by which mechanism the O2 production becomes favorable in alkaline solution.
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