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Classical and semiclassical dynamics in statistical environments with a mixed dynamical and statistical representation

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Phys. Chem. Chem. Phys., 2016, Advance Article
DOI: 10.1039/C5CP06161J, Paper
Kazuo Takatsuka, Kentaro Matsumoto
We present a basic theory to study real-time chemical dynamics embedded in a statistically treated large environment. It is shown that dynamically treated molecules should run on the free-energy functional surface, if and only if the spatial gradients of temperature functional are all zero.
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