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Evidence for the existence of Li2S2 clusters in lithium-sulfur batteries: ab initio Raman spectroscopy simulation

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Phys. Chem. Chem. Phys., 2015, Advance Article
DOI: 10.1039/C5CP02781K, Paper
Pouya Partovi-Azar, Thomas D. Kuhne, Payam Kaghazchi
Using density functional theory calculations and ab initio molecular dynamics simulations, we have observed a clear evidence of Li2S4 [rightward arrow] Li2S2 transition by studying systematic changes in the simulated Raman spectra of (Li2S4)n, n = 1, 4, and 8, towards that of (Li2S2)8.
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