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Rotational spectroscopy of methyl benzoylformate and methyl mandelate: structure and internal dynamics of a model reactant and product of enantioselective reduction

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Phys. Chem. Chem. Phys., 2015, Advance Article
DOI: 10.1039/C5CP03114A, Paper
Elijah G. Schnitzler, Mohammad Reza Poopari, Yunjie Xu, Wolfgang Jager
Rotational spectra of a prochiral ester, methyl benzoylformate, and the product of its enantioselective reduction, (R)-(-)-methyl mandelate, were measured, and minimum energy conformers and methyl rotation barriers were determined.
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