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R vs. S fluoroproline ring substitution: trans/cis effects on the formation of b2 ions in gas-phase peptide fragmentation

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Phys. Chem. Chem. Phys., 2016, 18,2202-2209
DOI: 10.1039/C5CP05155J, Paper
Matthew C. Bernier, Julia Chamot-Rooke, Vicki H. Wysocki
The b2 structures of model systems Val-Flp/flp-Ala and Tyr-Flp/flp-Ala were studied by action IRMPD spectroscopy to determine whether proline ring substitution guides ratios of diketopiperazine vs. oxazolone products.
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