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Comparison of [small pi]-hole tetrel bonding with [sigma]-hole halogen bonds in complexes of XCN (X = F, Cl, Br, I) and NH3

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Phys. Chem. Chem. Phys., 2016, Advance Article
DOI: 10.1039/C5CP07545A, Paper
Vincent de Paul N. Nziko, Steve Scheiner
In addition to the standard halogen bond formed when NH3 approaches XCN (X = F, Cl, Br, I) along its molecular axis, a perpendicular approach is also possible, toward a [small pi]-hole that is present above the X-C bond.
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