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Direct observation of vinyl hydroperoxide

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Phys. Chem. Chem. Phys., 2015, 17,20490-20494
DOI: 10.1039/C5CP02917A, Communication
Fang Liu, Yi Fang, Manoj Kumar, Ward H. Thompson, Marsha I. Lester
A doubly hydrogen-bonded interaction between the Criegee intermediate and a deuterated carboxylic acid facilitates efficient H/D transfer to yield a partially deuterated vinyl hydroperoxide.
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